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1 article(s) from Hosokai, Takuya

Development of fluorinated benzils and bisbenzils as room-temperature phosphorescent molecules

Shigeyuki Yamada,
Takuya Higashida,
Yizhou Wang,
Masato Morita,
Takuya Hosokai,
Kaveendra Maduwantha,
Kaveenga Rasika Koswattage and
Tsutomu Konno

Beilstein J. Org. Chem. 2020, 16, 1154–1162, doi:10.3762/bjoc.16.102

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Figure 1: (A) Transition-metal-containing and (B) pure organic phosphorescent materials reported thus far (bp...

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Figure 2: (A) Chemical structures of fluorescent bistolane derivatives previously developed by our group and ...

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Scheme 1: Synthetic pathway for fluorinated benzil (2) and bisbenzil (3) derivatives.

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Scheme 2: Proposed mechanism of Pd(II)-catalyzed alkyne oxidation by dimethyl sulfoxide (DMSO).

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Figure 3: Mulliken charge distributions of fluorinated 1a and nonfluorinated 1c obtained from density functio...

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Figure 4: Absorption and photoluminescence (PL) spectra of (A) 2a, (B) 2b, (C) 3a, (D) 3b, and (E) 3c in tolu...

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Figure 5: Distributions of molecular orbitals (isosurface value: 0.04 a.u.) involved in vertical electronic t...

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Published 29 May 2020

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